(Chalmers University of Technology/EurekAlert!) A research team led by Chalmers University of Technology, Sweden, have presented a new way to produce hydrogen gas without the scarce and expensive metal platinum. Using sunlight, water and tiny particles of electrically conductive plastic, the researchers show how the hydrogen can be produced efficiently, sustainably and at low cost.
Hydrogen plays a key role in the global pursuit for renewable energy. Although its use produces only water as a by-product, significant challenges remain before hydrogen can be produced both on a large-scale and in an environmentally friendly way.
A major challenge is the use of the metal platinum as a co-catalyst when sunlight and water are used to produce hydrogen. The Earth’s reserves of platinum are limited, and extraction is associated with risks to both the environment and to human health. Moreover, the production is concentrated in only a few countries, for example South Africa and Russia.
In a new study, published in the scientific journal Advanced Materials, a research team led by Professor Ergang Wang at Chalmers, show how solar energy can be used to produce hydrogen gas efficiently – and completely without platinum.
The process, Chalmers researcher Alexandre Holmes explains, involves quantities of tiny particles of electrically conductive plastic. Immersed in water, the particles interact both with sunlight and with their surroundings.
"Developing efficient photocatalysts without platinum has been a long-standing dream in this field. By applying advanced materials design to our conducting-plastic particles, we can produce hydrogen efficiently and sustainably without platinum – at radically lower cost, and with performance that can even surpass platinum-based systems", says Holmes, who together with Jingwen Pan from Jiefang Zhu’s group at Uppsala University, is the joint first author of the paper.
Cured fear of water behind the success
Efforts to overcome the platinum bottleneck have been underway for several years in Wang's research group at Chalmers.
The key to the new approach lies in advanced materials design of the electrically conductive plastic used in the process. This type of plastic, known as conjugated polymers, absorbs light efficiently, but is typically less compatible with water.
By adjusting the material properties at the molecular level, the researchers made the material much more water compatible.
“We also developed a way to form the plastic into nanoparticles that can enhance the interactions with water and boost the light-to-hydrogen process. The improvement comes from more loosely packed, more hydrophilic polymer chains inside the particles”, says Holmes.
In the reactor at the chemistry laboratory at Chalmers, bubbles of hydrogen gas can be easily seen with the naked eye as they form – showing that photocatalysis is happening efficiently.
When a lamp with simulated sunlight is directed at a beaker of water containing the nanoparticles, small bubbles of hydrogen gas almost immediately begin to form and rise through the water. The bubbles are collected and guided through tubes to a storage container, and the amount of gas produced can be monitored in real time.
“With as little as one gram of the polymer material, we can produce 30 litres of hydrogen in one hour”, says Holmes.
Avoiding another expensive ingredient: vitamin C
The next major step for Wang’s group will be to make the hydrogen process work using only sunlight and water, without any added helper chemicals.
Currently, they use vitamin C, which acts as a so-called sacrificial antioxidant. By donating electrons, it prevents the reaction from stalling, which in the laboratory can show high hydrogen production rates.
To realise truly sustainable solar hydrogen, Professor Wang explains, the goal is to split water molecules into hydrogen and oxygen simultaneously, with sunlight and water as the only inputs.
“Removing the need for platinum in this system is an important step towards sustainable hydrogen production for society. Now we are starting to explore materials and strategies aimed at achieving overall water splitting without additives. That will need a few more years, but we believe we are on the right track”, says research leader Ergang Wang, professor at the Department of Chemistry and Chemical Engineering at Chalmers.
High-resolution images and a video clip from the lab can be downloaded via this link.
More about the scientific article:
The study Highly Efficient Platinum-Free Photocatalytic Hydrogen Evolution From Low-cost Conjugated Polymer Nanoparticles has been published in Advanced Materials. The article is written by Alexandre Holmes, Jingwen Pan, Li Wang, Leandro Franco, Rafael R. Bicudo, Bo Albinsson, C. Moyses Araujo, Weiguo Zhu, Dongbo Wang, Thuc-Quyen Nguyen, Jiefang Zhu and Ergang Wang. At the time of the study, the researchers were active at Chalmers University of Technology, Uppsala University and Karlstad University in Sweden, University of São Paulo in Brazil, Harbin Institute of Technology and Changzhou University in China and the University of California in the USA.
The research has been funded by the Swedish Research Council, Formas, the Swedish Energy Agency and the Wallenberg Foundations.
More about electrically conductive plastic:
Electrically conductive plastic is also known as conjugated polymers. Conjugated polymers are semiconducting materials analogous to inorganic semiconductors such as silicon. This semiconducting nature makes it possible to manufacture a new type of technology – organic electronics – which can be used in many different areas such as energy conversion and storage, wearable electronics, electronic textiles and biotechnology in connection with or near the body.
Research has been conducted for a long time to make conjugated polymers stable and improve their electrically conductive properties.
The discovery that certain types of plastic can conduct electricity was made in the 1970s and was awarded the Nobel Prize in Chemistry in 2000. The laureates were Alan J. Heeger, Alan G. MacDiarmid and Hideki Shirakawa.
Briefly about hydrogen:
Hydrogen is an energy carrier that is used to transport, store and provide energy, just like electricity. Hydrogen can be produced from different types of energy sources: fossil, fossil-free, renewable. Hydrogen has great potential in renewable energy systems, where it can produced from, for example, sunlight or wind. Hydrogen is currently used worldwide to store solar and wind power, make homes self-sufficient in energy and as a vehicle fuel without harmful emissions.
Read more on the Hydrogen Sweden website. READ MORE
Related articles
- Highly Efficient Platinum-Free Photocatalytic Hydrogen Evolution From Low-cost Conjugated Polymer Nanoparticles (Advanced Materials)
- The recipe that lets electrically conductive plastic connect your body (Chalmers University of Technology)
- Open-flask, ambient temperature direct arylation synthesis of mixed ionic-electronic conductors (Science Advances)
Excerpt from Chalmers University of Technology: Electrically conductive plastic is a material that can be used for everything from sensors that monitor our health to self-cooling clothing or electronic stickers on the skin that send values directly to your mobile phone. Now researchers at Chalmers present a groundbreaking recipe for making it easier to manufacture the sought-after plastic in larger quantities and without toxic chemicals – in a more cost-effective way.
“When we get up to volume, we can work with the material in a completely different way. Larger quantities are required to be able to develop the various areas of use that exist, for example in biotechnology, energy storage and portable electronics,” says Christian Müller, professor at the Department of Chemistry and Chemical Engineering and scientific leader of a study recently published in Science Advances.
In the lab in the chemistry building at Chalmers, doctoral student Joost Kimpel shows the gold-glittering mass that can be easily shaped by gloved fingers. One hundred grams of the electrically conductive plastic would cost around one million kronor on the market today; about ten times as much as real gold. But for the human body, it is precisely the absence of metals that makes the material so valuable.
– While some metals can rust in humid environments, electrically conductive plastic is an organic material that feels good in the body and that the body feels good with. The material is reminiscent of the body's own tissues, while being a semiconductor. It is also an environmental advantage that you do not need to use the rare earth metals required for today's electronics, says Joost Kimpel, lead author of the new study.
Connected electronic stickers
There is great interest in electrically conductive plastics, or conjugated polymers as they are scientifically known, and their applications are numerous – not least in biotechnology. According to the researchers, these could include sensors that monitor disease states, provide information about fitness and health, or deliver drugs for difficult-to-treat diseases. With such technology, the body can be connected to other portable electronics, and even our mobile phones.
...
Unexpected lab result behind the progress
The key to the new manufacturing method, however, was found by a happy accident – during a routine experiment in the lab. When a chemical reaction went too fast and the plastic became ready too quickly, the idea of lowering the heat in the process came up. This was the starting point that led to the material now being manufactured at room temperature – in significantly fewer steps, with lower energy consumption and without toxic chemicals.
– The ingredients in our “recipe” are mild and can be used in industry, unlike the highly toxic substances that must be used today. Avoiding toxins in manufacturing means a safer working environment for staff, gives consumers peace of mind and facilitates recycling. In addition, costs can be radically reduced, since toxic substances require advanced handling, not least when it comes to protective procedures, storage and disposal of residual products, says Joost Kimpel.
Great interest in the new method
Although the study is brand new, the researchers have already noticed a lot of interest, not least because many researchers from other universities have gotten in touch. They now hope that the new manufacturing method will be able to bring electrically conductive plastic into society.
– An important discovery from this study is that the production method makes the electrically conductive plastic much better, which also means that electronics using these materials can become more powerful, says Christian Müller.
The next step in the research will be to work further on a method that makes it possible to produce even larger volumes – without interruption and with exactly the same results every time.
– The possibilities are great, but it is up to society and the market what is developed. It is a big step from lab to industry, but we hope that the new manufacturing method will be able to contribute a lot of benefit, says Christian Müller. READ MORE
Nearly 55,000 articles in our online library!
Use the categories and tags listed below to access the nearly 50,000 articles indexed on this website.
Advanced Biofuels USA Policy Statements and Handouts!
- For Kids: Carbon Cycle Puzzle Page
- Why Ethanol? Why E85?
- Just A Minute 3-5 Minute Educational Videos
- 30/30 Online Presentations
- “Disappearing” Carbon Tax for Non-Renewable Fuels
- What’s the Difference between Biodiesel and Renewable (Green) Diesel? 2020 revision
- How to De-Fossilize Your Fleet: Suggestions for Fleet Managers Working on Sustainability Programs
- New Engine Technologies Could Produce Similar Mileage for All Ethanol Fuel Mixtures
- Action Plan for a Sustainable Advanced Biofuel Economy
- The Interaction of the Clean Air Act, California’s CAA Waiver, Corporate Average Fuel Economy Standards, Renewable Fuel Standards and California’s Low Carbon Fuel Standard
- Latest Data on Fuel Mileage and GHG Benefits of E30
- What Can I Do?
Donate
DonateARCHIVES
- January 2026
- December 2025
- November 2025
- October 2025
- September 2025
- August 2025
- July 2025
- June 2025
- May 2025
- April 2025
- March 2025
- February 2025
- January 2025
- December 2024
- November 2024
- October 2024
- September 2024
- August 2024
- July 2024
- June 2024
- May 2024
- April 2024
- March 2024
- February 2024
- January 2024
- December 2023
- November 2023
- October 2023
- September 2023
- August 2023
- July 2023
- June 2023
- May 2023
- April 2023
- March 2023
- February 2023
- January 2023
- December 2022
- November 2022
- October 2022
- September 2022
- August 2022
- July 2022
- June 2022
- May 2022
- April 2022
- March 2022
- February 2022
- January 2022
- December 2021
- November 2021
- October 2021
- September 2021
- August 2021
- July 2021
- June 2021
- May 2021
- April 2021
- March 2021
- February 2021
- January 2021
- December 2020
- November 2020
- October 2020
- September 2020
- August 2020
- July 2020
- June 2020
- May 2020
- April 2020
- March 2020
- February 2020
- January 2020
- December 2019
- November 2019
- October 2019
- September 2019
- August 2019
- July 2019
- June 2019
- May 2019
- April 2019
- March 2019
- February 2019
- January 2019
- December 2018
- November 2018
- October 2018
- September 2018
- August 2018
- July 2018
- June 2018
- May 2018
- April 2018
- March 2018
- February 2018
- January 2018
- December 2017
- November 2017
- October 2017
- September 2017
- August 2017
- July 2017
- June 2017
- May 2017
- April 2017
- March 2017
- February 2017
- January 2017
- December 2016
- November 2016
- October 2016
- September 2016
- August 2016
- July 2016
- June 2016
- May 2016
- April 2016
- March 2016
- February 2016
- January 2016
- December 2015
- November 2015
- October 2015
- September 2015
- August 2015
- July 2015
- June 2015
- May 2015
- April 2015
- March 2015
- February 2015
- January 2015
- December 2014
- November 2014
- October 2014
- September 2014
- August 2014
- July 2014
- June 2014
- May 2014
- April 2014
- March 2014
- February 2014
- January 2014
- December 2013
- November 2013
- October 2013
- September 2013
- August 2013
- July 2013
- June 2013
- May 2013
- April 2013
- March 2013
- February 2013
- January 2013
- December 2012
- November 2012
- October 2012
- September 2012
- August 2012
- July 2012
- June 2012
- May 2012
- April 2012
- March 2012
- February 2012
- January 2012
- December 2011
- November 2011
- October 2011
- September 2011
- August 2011
- July 2011
- June 2011
- May 2011
- April 2011
- March 2011
- February 2011
- January 2011
- December 2010
- November 2010
- October 2010
- September 2010
- August 2010
- July 2010
- June 2010
- May 2010
- April 2010
- March 2010
- February 2010
- January 2010
- December 2009
- November 2009
- October 2009
- September 2009
- August 2009
- July 2009
- June 2009
- May 2009
- April 2009
- March 2009
- February 2009
- January 2009
- December 2008
- November 2008
- October 2008
- September 2008
- August 2008
- July 2008
- June 2008
- May 2008
- April 2008
- March 2008
- February 2008
- January 2008
- December 2007
- November 2007
- October 2007
- September 2007
- August 2007
- June 2007
- February 2007
- January 2007
- October 2006
- April 2006
- January 2006
- April 2005
- December 2004
- November 2004
- December 1987
CATEGORIES
- About Us
- Advanced Biofuels Call to Action
- Aviation Fuel/Sustainable Aviation Fuel (SAF)
- BioChemicals/Renewable Chemicals
- BioRefineries/Renewable Fuel Production
- Business News/Analysis
- Cooking Fuel
- Education
- 30/30 Online Presentations
- Competitions, Contests
- Earth Day 2021
- Earth Day 2022
- Earth Day 2023
- Earth Day 2024
- Earth Day 2025
- Executive Training
- Featured Study Programs
- Instagram TikTok Short Videos
- Internships
- Just a Minute
- K-12 Activities
- Mechanics training
- Online Courses
- Podcasts
- Scholarships/Fellowships
- Teacher Resources
- Technical Training
- Technician Training
- University/College Programs
- Events
- Coming Events
- Completed Events
- More Coming Events
- Requests for Speakers, Presentations, Posters
- Requests for Speakers, Presentations, Posters Completed
- Webinars/Online
- Webinars/Online Completed; often available on-demand
- Federal Agency/Executive Branch
- Agency for International Development (USAID)
- Agriculture (USDA)
- Commerce Department
- Commodity Futures Trading Commission
- Congressional Budget Office
- Defense (DOD)
- Air Force
- Army
- DARPA (Defense Advance Research Projects Agency)
- Defense Logistics Agency
- Marines
- Navy
- Education Department
- Energy (DOE)
- Environmental Protection Agency
- Federal Energy Regulatory Commission (FERC)
- Federal Reserve System
- Federal Trade Commission
- Food and Drug Administration
- General Services Administration
- Government Accountability Office (GAO)
- Health and Human Services (HHS)
- Homeland Security
- Housing and Urban Development (HUD)
- Interior Department
- International Trade Commission
- Joint Office of Energy and Transportation
- Justice (DOJ)
- Labor Department
- National Academies of Sciences Engineering Medicine
- National Aeronautics and Space Administration
- National Oceanic and Atmospheric Administration
- National Research Council
- National Science Foundation
- National Transportation Safety Board (NTSB)
- Occupational Safety and Health Administration
- Overseas Private Investment Corporation
- Patent and Trademark Office
- Securities and Exchange Commission
- State Department
- Surface Transportation Board
- Transportation (DOT)
- Federal Aviation Administration
- National Highway Traffic Safety Administration (NHTSA)
- Pipeline and Hazardous Materials Safety Admin (PHMSA)
- Treasury Department
- U.S. Trade Representative (USTR)
- White House
- Federal Legislation
- Federal Litigation
- Federal Regulation
- Feedstocks
- Agriculture/Food Processing Residues nonfield crop
- Alcohol/Ethanol/Isobutanol
- Algae/Other Aquatic Organisms/Seaweed
- Atmosphere
- Carbon Dioxide (CO2)
- Field/Orchard/Plantation Crops/Residues
- Forestry/Wood/Residues/Waste
- hydrogen
- Manure
- Methane/Biogas
- methanol/bio-/renewable methanol
- Not Agriculture
- RFNBO (Renewable Fuels of Non-Biological Origin)
- Seawater
- Sugars
- water
- Funding/Financing/Investing
- grants
- Green Jobs
- Green Racing
- Health Concerns/Benefits
- Heating Oil/Fuel
- History of Advanced Biofuels
- Infrastructure
- Aggregation
- Biofuels Engine Design
- Biorefinery/Fuel Production Infrastructure
- Carbon Capture/Storage/Use
- certification
- Deliver Dispense
- Farming/Growing
- Precursors/Biointermediates
- Preprocessing
- Pretreatment
- Terminals Transport Pipelines
- International
- Abu Dhabi
- Afghanistan
- Africa
- Albania
- Algeria
- Angola
- Antarctica
- Arctic
- Argentina
- Armenia
- Aruba
- Asia
- Asia Pacific
- Australia
- Austria
- Azerbaijan
- Bahamas
- Bahrain
- Bangladesh
- Barbados
- Belarus
- Belgium
- Belize
- Benin
- Bermuda
- Bhutan
- Bolivia
- Bosnia and Herzegovina
- Botswana
- Brazil
- Brunei
- Bulgaria
- Burkina Faso
- Burundi
- Cambodia
- Cameroon
- Canada
- Canary Islands
- Caribbean
- Central African Republic
- Central America
- Chad
- Chile
- China
- Colombia
- Congo
- Congo, Democratic Republic of
- Costa Rica
- Croatia
- Cuba
- Cyprus
- Czech Republic
- Denmark
- Dominican Republic
- Dubai
- Ecuador
- Egypt
- El Salvador
- Equatorial Guinea
- Estonia
- Eswatini/Swaziland
- Ethiopia
- European Union (EU)
- Fiji
- Finland
- France
- French Guiana
- Gabon
- Georgia
- Germany
- Ghana
- Global South
- Greece
- Greenland
- Grenada
- Guatemala
- Guinea
- Guyana
- Haiti
- Honduras
- Hong Kong
- Hungary
- Iceland
- India
- Indonesia
- Iran
- Iraq
- Ireland
- Israel
- Italy
- Ivory Coast
- Jamaica
- Japan
- Jersey
- Jordan
- Kazakhstan
- Kenya
- Korea
- Kosovo
- Kuwait
- Laos
- Latin America
- Latvia
- Lebanon
- Liberia
- Lithuania
- Luxembourg
- Macedonia
- Madagascar
- Malawi
- Malaysia
- Maldives
- Mali
- Malta
- Marshall Islands
- Mauritania
- Mauritius
- Mexico
- Middle East
- Moldova
- Monaco
- Mongolia
- Morocco
- Mozambique
- Myanmar/Burma
- Namibia
- Nepal
- Netherlands
- New Guinea
- New Zealand
- Nicaragua
- Niger
- Nigeria
- North Africa
- North America
- North Korea
- Northern Ireland
- Norway
- Oman
- Pakistan
- Panama
- Papua New Guinea
- Paraguay
- Peru
- Philippines
- Poland
- Portugal
- Qatar
- Republic of
- Romania
- Russia
- Rwanda
- Saudi Arabia
- Scotland
- Senegal
- Serbia
- Sierra Leone
- Singapore
- Slovakia/Slovak Republic
- Slovenia
- Solomon Islands
- South Africa
- South America
- South Korea
- South Sudan
- Southeast Asia
- Spain
- Sri Lanka
- Sudan
- Suriname
- Sweden
- Switzerland
- Taiwan
- Tanzania
- Thailand
- Timor-Leste
- Togo
- Trinidad and Tobago
- Tunisia
- Turkey
- Uganda
- UK (United Kingdom)
- Ukraine
- United Arab Emirates UAE
- Uruguay
- Uzbekistan
- Vatican
- Venezuela
- Vietnam
- Wales
- Zambia
- Zanzibar
- Zimbabwe
- Marine/Boat Bio and Renewable Fuel/MGO/MDO/SMF
- Marketing/Market Forces and Sales
- Opinions
- Organizations
- Original Writing, Opinions Advanced Biofuels USA
- Policy
- Presentations
- Biofuels Digest Conferences
- DOE Conferences
- Bioeconomy 2017
- Bioenergy2015
- Biomass2008
- Biomass2009
- Biomass2010
- Biomass2011
- Biomass2012
- Biomass2013
- Biomass2014
- DOE Project Peer Review
- Other Conferences/Events
- R & D Focus
- Carbon Capture/Storage/Use
- Co-Products
- Feedstock
- Logistics
- Performance
- Process
- Vehicle/Engine/Motor/Aircraft/Boiler/Ship
- Yeast
- Railroad/Train/Locomotive Fuel
- Resources
- Books Web Sites etc
- Business
- Definition of Advanced Biofuels
- Find Stuff
- Government Resources
- Scientific Resources
- Technical Resources
- Tools/Decision-Making
- Rocket/Missile Fuel
- Sponsors
- States
- Alabama
- Alaska
- Arizona
- Arkansas
- California
- Colorado
- Connecticut
- Delaware
- Florida
- Georgia
- Hawai'i
- Idaho
- Illinois
- Indiana
- Iowa
- Kansas
- Kentucky
- Louisiana
- Maine
- Maryland
- Massachusetts
- Michigan
- Midwest
- Minnesota
- Mississippi
- Missouri
- Montana
- Native American tribal nation lands
- Nebraska
- Nevada
- New Hampshire
- New Jersey
- New Mexico
- New York
- North Carolina
- North Dakota
- Ohio
- Oklahoma
- Oregon
- Pennsylvania
- Puerto Rico
- Rhode Island
- South Carolina
- South Dakota
- Tennessee
- Texas
- Utah
- Vermont
- Virginia
- Washington
- Washington DC
- West Coast
- West Virginia
- Wisconsin
- Wyoming
- Sustainability
- Uncategorized
- What You Can Do
tags
© 2008-2023 Copyright Advanced BioFuels USA. All Rights reserved.
Comments are closed.