Scientists Show a Single Catalyst Can Perform the First Step of Turning CO2 into Fuel in Two Very Different Ways

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August 9, 2021

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by Glennda Chui (SLAC National Accelerator Laboratory) Their work aims to bridge two approaches to driving the reaction – one powered by heat, the other by electricity – with the goal of discovering more efficient and sustainable ways to convert carbon dioxide into useful products.

Virtually all chemical and fuel production relies on catalysts, which accelerate chemical reactions without being consumed in the process. Most of these reactions take place in huge reactor vessels and may require high temperatures and pressures.

Scientists have been working on alternative ways to drive these reactions with electricity, rather than heat. This could potentially allow cheap, efficient, distributed manufacturing powered by renewable sources of electricity.

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Scientists at Stanford University and the Department of Energy’s SLAC National Accelerator Laboratory reported today (August 4, 2021) that they have made a new catalyst that works with either heat or electricity. Based on nickel atoms, the catalyst accelerates a reaction for turning carbon dioxide into carbon monoxide – the first step in making fuels and useful chemicals from CO₂.

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The results also explain how the new catalyst drives this key reaction faster when used in an electrochemical reactor, the research team said. Their report appeared in the print edition of Angewandte Chemie this week.

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The active parts of the catalyst – the places where it grabs passing molecules, gets them to react and releases the products – consist of individual nickel atoms bonded to nitrogen atoms that are scattered throughout the carbon material. READ MORE

David M. Koshy et al., Angewandte Chemie, 06 April 2021 (10.1002/anie.202101326)

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