Advanced BioFuels USA

(University of Illinois at Urbana-Champaign/Phys.Org) Surplus industrial carbon dioxide creates an opportunity to convert waste into a valuable commodity. Excess CO2 can be a feedstock for chemicals typically derived from fossil fuels, but the process is energy-intensive and expensive. University of Illinois chemical engineers have assessed the technical and economic feasibility of a new electrolysis technology that uses a cheap biofuel byproduct to reduce the energy consumption of the waste-to-value process by 53 percent.

The new findings are published in the journal Nature Energy.

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“About 90 percent of the energy required in conventional CO2 reduction is used up by the oxygen-producing, anode side of an electrolysis cell,” said Paul Kenis, a chemical and biomolecular engineering professor, department chair and study co-author. “But there is no big market for the excess oxygen, so 90 percent of the energy is essentially wasted.”

Finding a feed material that reduces the energy to drive the anode reaction could be a strategy for radically reducing the energy requirements of CO2 conversion, according to a recent National Academies Report of which Kenis was a co-author.

The new study proposes glycerol—an organic byproduct of sugar cane biofuel production that requires less energy to oxidize—as an alternative to the energy-intensive oxygen-producing step.

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“Being able to drive CO2 conversion with already-in-place infrastructure—and not relying on the hope of the future grid being powered by 100 percent renewables—while achieving carbon neutrality or negativity could be a holy grail scenario.”

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“The glycerol-based electrolysis reaction shows a lot of promise. However, we will continue to explore other organic waste materials because even when production rises in the wake of increased biofuel production, it still will not be enough to fully support the need,” Kenis said. “The good news is that the chemistry involved is flexible and there are a lot of organic waste products that can do the job.”

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Many researchers focus on improving the selectivity and activity of chemical catalysts for CO2 reduction reactions, and that work needs to continue, said Sumit Verma, a former chemical and biomolecular engineering graduate student and study co-author. “Looking beyond oxygen evolution at the anode seems like a win-win situation, as we not only reduce the processes’ energy consumption but also produce a second valuable product stream,” he said. READ MORE

Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption (Nature Energy)